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Acceleration of CO(2) insertion into metal hydrides: ligand, Lewis acid, and solvent effects on reaction kinetics
The insertion of CO(2) into metal hydrides and the microscopic reverse decarboxylation of metal formates are important elementary steps in catalytic cycles for both CO(2) hydrogenation to formic acid and methanol as well as formic acid and methanol dehydrogenation. Here, we use rapid mixing stopped-...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115618/ https://www.ncbi.nlm.nih.gov/pubmed/30310595 http://dx.doi.org/10.1039/c8sc02535e |