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Acceleration of CO(2) insertion into metal hydrides: ligand, Lewis acid, and solvent effects on reaction kinetics

The insertion of CO(2) into metal hydrides and the microscopic reverse decarboxylation of metal formates are important elementary steps in catalytic cycles for both CO(2) hydrogenation to formic acid and methanol as well as formic acid and methanol dehydrogenation. Here, we use rapid mixing stopped-...

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Detalles Bibliográficos
Autores principales:	Heimann, Jessica E., Bernskoetter, Wesley H., Hazari, Nilay, Mayer, James M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115618/ https://www.ncbi.nlm.nih.gov/pubmed/30310595 http://dx.doi.org/10.1039/c8sc02535e

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