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Nitric oxide activation facilitated by cooperative multimetallic electron transfer within an iron-functionalized polyoxovanadate–alkoxide cluster

A series of NO-bound, iron-functionalized polyoxovanadate–alkoxide (FePOV–alkoxide) clusters have been synthesized, providing insight into the role of multimetallic constructs in the coordination and activation of a substrate. Upon exposure of the heterometallic cluster to NO, the vanadium-oxide met...

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Detalles Bibliográficos
Autores principales: Li, F., Meyer, R. L., Carpenter, S. H., VanGelder, L. E., Nichols, A. W., Machan, C. W., Neidig, M. L., Matson, E. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115649/
https://www.ncbi.nlm.nih.gov/pubmed/30310566
http://dx.doi.org/10.1039/c8sc00987b