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Diverse secondary C(sp(3))–H bond functionalization via site-selective trifluoroacetoxylation of aliphatic amines

We describe a coinage-metal-catalyzed site-selective oxidation of secondary C(sp(3))–H bonds for aliphatic amine substrates. Broad amine scope, good functional compatibility and late-stage diversification are demonstrated with this method. The steric demand of the β-substituents controlled diastereo...

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Detalles Bibliográficos
Autores principales:	Tang, Yongzhen, Qin, Yuman, Meng, Dongmei, Li, Chaoqun, Wei, Junfa, Yang, Mingyu
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115674/ https://www.ncbi.nlm.nih.gov/pubmed/30310565 http://dx.doi.org/10.1039/c8sc01788c

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