Cargando…

Rhodium catalyzed cascade cyclization featuring B–H and C–H activation: one-step construction of carborane-fused N-polyheterocycles

A one-pot strategy for efficient and facile synthesis of C,B-substituted carborane-fused N-polyheterocycles is reported. A rhodium catalyzed cascade cyclization of carboranyl N-arylimines with vinyl ketones enables the effective construction of three new B–C and C–C bonds in one reaction. Both carbo...

Descripción completa

Detalles Bibliográficos
Autores principales: Lyu, Hairong, Quan, Yangjian, Xie, Zuowei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115682/
https://www.ncbi.nlm.nih.gov/pubmed/30310567
http://dx.doi.org/10.1039/c8sc01568f