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Silylated cyclopentadienes as competent silicon Lewis acid catalysts

The synthesis and characterization of silicon Lewis acid complexes that incorporate highly electron-deficient cyclopentadienes is reported. Several pentacarboxycyclopentadienyl and monocarboxytetracyanocyclopentadienyl complexes were prepared. A comparison of their reactivities for catalysis of the...

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Detalles Bibliográficos
Autores principales: Radtke, M. Alex, Lambert, Tristan H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115689/
https://www.ncbi.nlm.nih.gov/pubmed/30310569
http://dx.doi.org/10.1039/c8sc02279h