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Blob Size Controls Diffusion of Free Polymer in a Chemically Identical Brush in Semidilute Solution

[Image: see text] The diffusion of rhodamine-labeled poly(ethylene glycol) (r-PEG) within surface-grafted poly(ethylene glycol) (s-PEG) layers in aqueous solution at 18 °C was measured by fluorescence correlation spectroscopy. The diffusion coefficient of r-PEG within s-PEG was controlled by the gra...

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Detalles Bibliográficos
Autores principales: Zhang, Zhenyu J., Edmondson, Steve, Mears, Matthew, Madsen, Jeppe, Armes, Steven P., Leggett, Graham J., Geoghegan, Mark
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6117105/
https://www.ncbi.nlm.nih.gov/pubmed/30174342
http://dx.doi.org/10.1021/acs.macromol.8b01193