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A Free Silanide from Nucleophilic Substitution at Silicon(II)
A computationally guided synthetic route to a free silanide derived from tris(3‐methylindol‐2‐yl)methane ([(tmim)Si](−)) through nucleophilic substitution on the Si(II) precursor (Idipp)SiCl(2) is reported (Idipp=2,3‐dihydro‐1,3‐bis(2,6‐diisopropylphenyl)‐1H‐imidazol‐2‐ylidene). This approach circum...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6120461/ https://www.ncbi.nlm.nih.gov/pubmed/29577491 http://dx.doi.org/10.1002/chem.201801435 |