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A Free Silanide from Nucleophilic Substitution at Silicon(II)

A computationally guided synthetic route to a free silanide derived from tris(3‐methylindol‐2‐yl)methane ([(tmim)Si](−)) through nucleophilic substitution on the Si(II) precursor (Idipp)SiCl(2) is reported (Idipp=2,3‐dihydro‐1,3‐bis(2,6‐diisopropylphenyl)‐1H‐imidazol‐2‐ylidene). This approach circum...

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Detalles Bibliográficos
Autores principales:	Witteman, Léon, Evers, Tim, Lutz, Martin, Moret, Marc‐Etienne
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2018
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6120461/ https://www.ncbi.nlm.nih.gov/pubmed/29577491 http://dx.doi.org/10.1002/chem.201801435

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