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Strategic Isolation of a Polyoxocation Mimicking Vanadium(V) Oxide Layered-Structure by Stacking of [H(2)V(2)O(8)](4−) Anions Bridged by (1,4,7-Triazacyclononane)Co(III) Complexes
An isolation of a vanadium(V) oxide cluster mimicking V(2)O(5) layered structure was achieved formulated as [{Co(tacn)}(4)V(4)O(12)(OH)(4)](4+) (1) (tacn = 1,4,7-triazacyclononane). From the (51)V NMR spectra of the reaction mixtures, we optimized the reaction condition in terms of a molar ratio of...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Frontiers Media S.A.
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6121072/ https://www.ncbi.nlm.nih.gov/pubmed/30211155 http://dx.doi.org/10.3389/fchem.2018.00375 |