Cargando…
Cobalt-catalyzed nucleophilic addition of the allylic C(sp(3))–H bond of simple alkenes to ketones
We herein describe a cobalt/Xantphos-catalyzed regioselective addition of simple alkenes to acetophenone derivatives, affording branched homoallylic alcohols in high yields with perfect branch selectivities. The intermediate of the reaction would be a nucleophilic allylcobalt(I) species generated vi...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2018
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6122116/ https://www.ncbi.nlm.nih.gov/pubmed/30202455 http://dx.doi.org/10.3762/bjoc.14.176 |