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Cationic cobalt-catalyzed [1,3]-rearrangement of N-alkoxycarbonyloxyanilines

A cationic cobalt catalyst efficiently promoted the reaction of N-alkoxycarbonyloxyanilines at 30 °C, affording the corresponding ortho-aminophenols in good to high yields. As reported previously, our mechanistic studies including oxygen-18 labelling experiments indicate that the rearrangement of th...

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Detalles Bibliográficos
Autores principales: Nakamura, Itaru, Owada, Mao, Jo, Takeru, Terada, Masahiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6122159/
https://www.ncbi.nlm.nih.gov/pubmed/30202451
http://dx.doi.org/10.3762/bjoc.14.172