Novel photochemical reactions of carbocyclic diazodiketones without elimination of nitrogen – a suitable way to N-hydrazonation of C–H-bonds

The sensitized photoexcitation of 2-diazocyclopentane-1,3-diones in the presence of THF leads to the insertion of the terminal N-atom of the diazo group into the α-С–Н bond of THF, producing the associated N-alkylhydrazones in yields of up to 63–71%. Further irradiation of hydrazones derived from fu...

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Detalles Bibliográficos
Autores principales: Rodina, Liudmila L, Azarova, Xenia V, Medvedev, Jury J, Semenok, Dmitrij V, Nikolaev, Valerij A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6122312/
https://www.ncbi.nlm.nih.gov/pubmed/30202479
http://dx.doi.org/10.3762/bjoc.14.200

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6122312/
https://www.ncbi.nlm.nih.gov/pubmed/30202479
http://dx.doi.org/10.3762/bjoc.14.200

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