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Selective formation of a zwitterion adduct and bicarbonate salt in the efficient CO(2) fixation by N-benzyl cyclic guanidine under dry and wet conditions

The efficient CO(2) fixation by N-benzyl cyclic guanidine 1 was achieved by bubbling dry CO(2) through CH(3)CN at 25 °C for 2 h. In addition, the zwitterion adduct 2 and bicarbonate salt 3 were selectively prepared from 1 under dry (in anhydrous CH(3)CN) and wet (in CH(3)CN containing an equimolar a...

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Detalles Bibliográficos
Autores principales: Yoshida, Yoshiaki, Aoyagi, Naoto, Endo, Takeshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6122324/
https://www.ncbi.nlm.nih.gov/pubmed/30202473
http://dx.doi.org/10.3762/bjoc.14.194