Hypervalent iodine compounds for anti-Markovnikov-type iodo-oxyimidation of vinylarenes

The iodo-oxyimidation of styrenes with the N-hydroxyimide/I(2)/hypervalent iodine oxidant system was proposed. Among the examined hypervalent iodine oxidants (PIDA, PIFA, IBX, DMP) PhI(OAc)(2) proved to be the most effective; yields of iodo-oxyimides are 34–91%. A plausible reaction pathway includes...

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Detalles Bibliográficos
Autores principales: Krylov, Igor B, Paveliev, Stanislav A, Syroeshkin, Mikhail A, Korlyukov, Alexander A, Dorovatovskii, Pavel V, Zubavichus, Yan V, Nikishin, Gennady I, Terent’ev, Alexander O
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6122379/
https://www.ncbi.nlm.nih.gov/pubmed/30202467
http://dx.doi.org/10.3762/bjoc.14.188

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6122379/
https://www.ncbi.nlm.nih.gov/pubmed/30202467
http://dx.doi.org/10.3762/bjoc.14.188

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