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Divergent ring-opening coupling between cyclopropanols and alkynes under cobalt catalysis

Cobalt–diphosphine catalysts promote ring-opening coupling reactions between cyclopropanols and unactivated internal alkynes, affording either β-alkenyl ketones or multisubstituted cyclopentenol derivatives in good yields with good to excellent regioselectivities. The chemoselectivity between these...

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Detalles Bibliográficos
Autores principales: Yang, Junfeng, Shen, Yixiao, Lim, Yang Jie, Yoshikai, Naohiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6124909/
https://www.ncbi.nlm.nih.gov/pubmed/30210767
http://dx.doi.org/10.1039/c8sc02074d