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Crystal structure of [μ-1κ(2) C (1),C (4):2(1,2,3,4-η)-1,2,3,4-tetraphenylbuta-1,3-diene-1,4-diyl]bis(tricarbonylosmium)(Os—Os)
In the title complex C(34)H(20)O(6)Os(2) or (μ-η(4)-C(4)Ph(4))Os(2)(CO)(6), one Os atom is part of a metallacyclopentadiene ring, while the second Os atom is π-bonded to the organic portion of this ring. The distance of 2.7494 (2) Å between the two Os atoms is typical of an Os—Os single bond. Thr...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127685/ https://www.ncbi.nlm.nih.gov/pubmed/30225107 http://dx.doi.org/10.1107/S2056989018011179 |