A new structural model for NiFe hydrogenases: an unsaturated analogue of a classic hydrogenase model leads to more enzyme-like Ni—Fe distance and inter­planar fold

The complex cation in the title compound, (carbonyl-1κC)(1η(5)-penta­methyl­cyclo­penta­dien­yl)(μ-2,3,9,10-tetra­methyl-1,4,8,11-tetra­thia­undeca-2,9-diene-1,11-diido-1κ(2) S,S′′′:2κ(4) S,S′,S′′,S′′′)ironnickel(Fe—Ni) hexa­fluoro­phosphate, [FeNi(C(10)H(15))(C(11)H(18)S(4))(CO)]PF(6) or [Ni(L′)FeC...

Descripción completa

Detalles Bibliográficos
Autores principales: Harrison, Daniel J., Lough, Alan J., Fekl, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127701/
https://www.ncbi.nlm.nih.gov/pubmed/30225104
http://dx.doi.org/10.1107/S2056989018010939

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127701/
https://www.ncbi.nlm.nih.gov/pubmed/30225104
http://dx.doi.org/10.1107/S2056989018010939

Ejemplares similares