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A new structural model for NiFe hydrogenases: an unsaturated analogue of a classic hydrogenase model leads to more enzyme-like Ni—Fe distance and interplanar fold
The complex cation in the title compound, (carbonyl-1κC)(1η(5)-pentamethylcyclopentadienyl)(μ-2,3,9,10-tetramethyl-1,4,8,11-tetrathiaundeca-2,9-diene-1,11-diido-1κ(2) S,S′′′:2κ(4) S,S′,S′′,S′′′)ironnickel(Fe—Ni) hexafluorophosphate, [FeNi(C(10)H(15))(C(11)H(18)S(4))(CO)]PF(6) or [Ni(L′)FeC...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127701/ https://www.ncbi.nlm.nih.gov/pubmed/30225104 http://dx.doi.org/10.1107/S2056989018010939 |