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Crystal structures of the hexa­fluorido­phosphate salts of the isomeric 2-, 3- and 4-cyano-1-methyl­pyridinium cations and determination of solid-state inter­action energies

The synthesis and crystal structures of the isomeric mol­ecular salts 2-, 3- and 4-cyano-1-methyl­pyridinium hexa­fluorido­phosphate, C(7)H(7)N(2) (+)·PF(6) (−), are reported. In 2-cyano-1-methyl­pyridinium hexa­fluorido­phosphate, C—H⋯F hydrogen bonds form chains extending along the c-axis directio...

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Detalles Bibliográficos
Autores principales: Mague, Joel T., Larrabee, Erin, Olivier, David, Vaccaro, Francesca, Riley, Kevin E., Koplitz, Lynn V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127719/
https://www.ncbi.nlm.nih.gov/pubmed/30225126
http://dx.doi.org/10.1107/S2056989018011003