Regiospecific formation of the nitromethyl-substituted 3-phenyl-4,5-dihydroisoxazole via [3 + 2] cycloaddition

ABSTRACT: 5-(Nitromethyl)-3-phenyl-4,5-dihydroisoxazole was obtained as a product of a high-yielding [3 + 2] cycloaddition reaction of in situ-generated benzonitrile N-oxide and 3-nitroprop-1-ene. For the first time, the regiochemistry of this reaction was unambiguously proven by X-ray structural an...

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Detalles Bibliográficos
Autores principales: Mirosław, Barbara, Babyuk, Dmytro, Łapczuk-Krygier, Agnieszka, Kącka-Zych, Agnieszka, Demchuk, Oleg M., Jasiński, Radomir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2018
Materias:
Original Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6133101/
https://www.ncbi.nlm.nih.gov/pubmed/30237620
http://dx.doi.org/10.1007/s00706-018-2227-6

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6133101/
https://www.ncbi.nlm.nih.gov/pubmed/30237620
http://dx.doi.org/10.1007/s00706-018-2227-6

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