Anion-Initiated Trifluoromethylation by TMSCF(3): Deconvolution of the Siliconate–Carbanion Dichotomy by Stopped-Flow NMR/IR

[Image: see text] The mechanism of CF(3) transfer from R(3)SiCF(3) (R = Me, Et, iPr) to ketones and aldehydes, initiated by M(+)X(–) (<0.004 to 10 mol %), has been investigated by analysis of kinetics (variable-ratio stopped-flow NMR and IR), (13)C/(2)H KIEs, LFER, addition of ligands (18-c-6, cr...

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Detalles Bibliográficos
Autores principales: Johnston, Craig P., West, Thomas H., Dooley, Ruth E., Reid, Marc, Jones, Ariana B., King, Edward J., Leach, Andrew G., Lloyd-Jones, Guy C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6133236/
https://www.ncbi.nlm.nih.gov/pubmed/30080973
http://dx.doi.org/10.1021/jacs.8b06777

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6133236/
https://www.ncbi.nlm.nih.gov/pubmed/30080973
http://dx.doi.org/10.1021/jacs.8b06777

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