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Catalyst-dependent selectivity in sulfonium ylide cycloisomerization reactions

Divergent catalysis is an emerging field whereby access to structurally diverse compounds from a common precursor is achieved through controlled reaction pathways. Herein we present an unusual example of π-acid catalyst dependent selectivity in the cycloisomerization of alkene-tethered sulfonium yli...

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Detalles Bibliográficos
Autores principales: Oost, Rik, Neuhaus, James D., Misale, Antonio, Meyrelles, Ricardo, Veiros, Luís F., Maulide, Nuno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6137435/
https://www.ncbi.nlm.nih.gov/pubmed/30310629
http://dx.doi.org/10.1039/c8sc02815j