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Stereoselective total synthesis and structural revision of the diacetylenic diol natural products strongylodiols H and I
The stereoselective total synthesis of strongylodiol H and I has been accomplished. The synthetic procedure comprised the stereoselective reduction of a ketone functionality in an ene–yne–one employing CBS as a catalyst and a Cadiot–Chodkiewicz coupling reaction as the key reaction steps. A common a...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6142741/ https://www.ncbi.nlm.nih.gov/pubmed/30254695 http://dx.doi.org/10.3762/bjoc.14.206 |