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One-pot synthesis of epoxides from benzyl alcohols and aldehydes

A one-pot synthesis of epoxides from commercially available benzyl alcohols and aldehydes is described. The reaction proceeds through in situ generation of sulfonium salts from benzyl alcohols and their subsequent deprotonation for use in Corey–Chaykovsky epoxidation of aldehydes. The generality of...

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Detalles Bibliográficos
Autores principales: Alfonzo, Edwin, Mendoza, Jesse W L, Beeler, Aaron B
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6142752/
https://www.ncbi.nlm.nih.gov/pubmed/30254694
http://dx.doi.org/10.3762/bjoc.14.205