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Isolation and Characterization of Silyl Enol Ether Intermediates in the Synthesis of 5,6,9,10–Tetrahydro-7,8-benzocyclooctene-dione

The 5,6,9,10-tetrahydro-7,8-benzocyclooctenedione 4 has been synthesized through fragmentation of a bicyclo[4.2.0]octane system using an acyloin reaction on the trans-2,3-dicarboethoxy-1,2,3,4-tetrahydronaphthalene 1 in the presence of trimethyl-chlorosilane (TMCS). The two intermediates of this rea...

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Detalles Bibliográficos
Autores principales: Fakhri, Saeed Abolghassemi, Zenouz, Adeleh Moshtaghi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146440/
http://dx.doi.org/10.3390/71100801