Isolation and Characterization of Silyl Enol Ether Intermediates in the Synthesis of 5,6,9,10–Tetrahydro-7,8-benzocyclooctene-dione

The 5,6,9,10-tetrahydro-7,8-benzocyclooctenedione 4 has been synthesized through fragmentation of a bicyclo[4.2.0]octane system using an acyloin reaction on the trans-2,3-dicarboethoxy-1,2,3,4-tetrahydronaphthalene 1 in the presence of trimethyl-chlorosilane (TMCS). The two intermediates of this rea...

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Autores principales: Fakhri, Saeed Abolghassemi, Zenouz, Adeleh Moshtaghi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146440/
http://dx.doi.org/10.3390/71100801
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author Fakhri, Saeed Abolghassemi
Zenouz, Adeleh Moshtaghi
author_facet Fakhri, Saeed Abolghassemi
Zenouz, Adeleh Moshtaghi
author_sort Fakhri, Saeed Abolghassemi
collection PubMed
description The 5,6,9,10-tetrahydro-7,8-benzocyclooctenedione 4 has been synthesized through fragmentation of a bicyclo[4.2.0]octane system using an acyloin reaction on the trans-2,3-dicarboethoxy-1,2,3,4-tetrahydronaphthalene 1 in the presence of trimethyl-chlorosilane (TMCS). The two intermediates of this reaction, bis(trimethylsiloxy) derivatives 2 and 3, have been isolated and characterized.
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spelling pubmed-61464402018-11-19 Isolation and Characterization of Silyl Enol Ether Intermediates in the Synthesis of 5,6,9,10–Tetrahydro-7,8-benzocyclooctene-dione Fakhri, Saeed Abolghassemi Zenouz, Adeleh Moshtaghi Molecules Article The 5,6,9,10-tetrahydro-7,8-benzocyclooctenedione 4 has been synthesized through fragmentation of a bicyclo[4.2.0]octane system using an acyloin reaction on the trans-2,3-dicarboethoxy-1,2,3,4-tetrahydronaphthalene 1 in the presence of trimethyl-chlorosilane (TMCS). The two intermediates of this reaction, bis(trimethylsiloxy) derivatives 2 and 3, have been isolated and characterized. MDPI 2002-11-30 /pmc/articles/PMC6146440/ http://dx.doi.org/10.3390/71100801 Text en © 2002 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Fakhri, Saeed Abolghassemi
Zenouz, Adeleh Moshtaghi
Isolation and Characterization of Silyl Enol Ether Intermediates in the Synthesis of 5,6,9,10–Tetrahydro-7,8-benzocyclooctene-dione
title Isolation and Characterization of Silyl Enol Ether Intermediates in the Synthesis of 5,6,9,10–Tetrahydro-7,8-benzocyclooctene-dione
title_full Isolation and Characterization of Silyl Enol Ether Intermediates in the Synthesis of 5,6,9,10–Tetrahydro-7,8-benzocyclooctene-dione
title_fullStr Isolation and Characterization of Silyl Enol Ether Intermediates in the Synthesis of 5,6,9,10–Tetrahydro-7,8-benzocyclooctene-dione
title_full_unstemmed Isolation and Characterization of Silyl Enol Ether Intermediates in the Synthesis of 5,6,9,10–Tetrahydro-7,8-benzocyclooctene-dione
title_short Isolation and Characterization of Silyl Enol Ether Intermediates in the Synthesis of 5,6,9,10–Tetrahydro-7,8-benzocyclooctene-dione
title_sort isolation and characterization of silyl enol ether intermediates in the synthesis of 5,6,9,10–tetrahydro-7,8-benzocyclooctene-dione
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146440/
http://dx.doi.org/10.3390/71100801
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AT zenouzadelehmoshtaghi isolationandcharacterizationofsilylenoletherintermediatesinthesynthesisof56910tetrahydro78benzocyclooctenedione

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