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Stereoselective Synthesis of 5-7 membered Cyclic Ethers by Deiodonative Ring-Enlargement Using Hypervalent Iodine Reagents

Stereoselective synthesis of 5-7 membered cyclic ethers was achieved by deiodonative ring-enlargement of cyclic ethers having an iodoalkyl substituent. The reaction took place readily under mild conditions using hypervalent iodine compounds and an acetoxy or a trifluoroacetoxy group was introduced i...

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Detalles Bibliográficos
Autores principales: Abo, Tomohito, Sawaguchi, Masanori, Senboku, Hisanori, Hara, Shoji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147675/
https://www.ncbi.nlm.nih.gov/pubmed/18007285
http://dx.doi.org/10.3390/10010183