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Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement

Cyclophellitol and its C3-epimer have been synthesized from 5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeleton was constructed through a Ferrier-II reaction meditated by PdCl(2).

Detalles Bibliográficos
Autores principales: Takahashi, Hideyo, Ikegami, Shiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147719/
https://www.ncbi.nlm.nih.gov/pubmed/18007359
http://dx.doi.org/10.3390/10080901