Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement

Cyclophellitol and its C3-epimer have been synthesized from 5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeleton was constructed through a Ferrier-II reaction meditated by PdCl(2).

Detalles Bibliográficos
Autores principales: Takahashi, Hideyo, Ikegami, Shiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147719/
https://www.ncbi.nlm.nih.gov/pubmed/18007359
http://dx.doi.org/10.3390/10080901
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author Takahashi, Hideyo
Ikegami, Shiro
author_facet Takahashi, Hideyo
Ikegami, Shiro
author_sort Takahashi, Hideyo
collection PubMed
description Cyclophellitol and its C3-epimer have been synthesized from 5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeleton was constructed through a Ferrier-II reaction meditated by PdCl(2).
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spelling pubmed-61477192018-11-19 Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement Takahashi, Hideyo Ikegami, Shiro Molecules Article Cyclophellitol and its C3-epimer have been synthesized from 5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeleton was constructed through a Ferrier-II reaction meditated by PdCl(2). MDPI 2005-08-31 /pmc/articles/PMC6147719/ /pubmed/18007359 http://dx.doi.org/10.3390/10080901 Text en © 2005 by MDPI (http://www.mdpi.org). Reproduction is permitted for non commercial purposes.
spellingShingle Article
Takahashi, Hideyo
Ikegami, Shiro
Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement
title Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement
title_full Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement
title_fullStr Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement
title_full_unstemmed Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement
title_short Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement
title_sort synthesis of cyclophellitol utilizing a palladium chloride mediated-ferrier-ii rearrangement
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147719/
https://www.ncbi.nlm.nih.gov/pubmed/18007359
http://dx.doi.org/10.3390/10080901
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AT ikegamishiro synthesisofcyclophellitolutilizingapalladiumchloridemediatedferrieriirearrangement

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