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Synthesis Crystal Structure of a New Triosmium Alkylidyne Carbonyl Cluster Containing a Chiral Ferrocenylphosphine Ligand
The synthesis, spectroscopic characterization and X-ray crystal structure of a new chiral triosmium alkylidyne carbonyl cluster, (R,S)-[Os(3)(μ-H)(2)(CO)(9){μ(3)-CPPh(2)(η(5)-C(5)H(4))Fe(η(5)-C(5)H(3)(PPh(2))CH(Me)NMe(2))}] (1) are described. Compound 1 crystallizes in the non-centrosymmetric space...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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MDPI
2005
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6148507/ https://www.ncbi.nlm.nih.gov/pubmed/18007333 http://dx.doi.org/10.3390/10060640 |