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Synthesis Crystal Structure of a New Triosmium Alkylidyne Carbonyl Cluster Containing a Chiral Ferrocenylphosphine Ligand

The synthesis, spectroscopic characterization and X-ray crystal structure of a new chiral triosmium alkylidyne carbonyl cluster, (R,S)-[Os(3)(μ-H)(2)(CO)(9){μ(3)-CPPh(2)(η(5)-C(5)H(4))Fe(η(5)-C(5)H(3)(PPh(2))CH(Me)NMe(2))}] (1) are described. Compound 1 crystallizes in the non-centrosymmetric space...

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Detalles Bibliográficos
Autor principal: Wong, Wai-Yeung
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6148507/
https://www.ncbi.nlm.nih.gov/pubmed/18007333
http://dx.doi.org/10.3390/10060640