Mechanistic Study of Copper-Catalyzed C-H Hydroxylation/C-S Coupling by ESI-HR MS and DFT Calculations

The reaction mechanism of Cu-catalyzed C-H hydroxylation/C-S coupling was studied using electrospray ionization high resolution mass spectrometry (ESI-HR MS) and density functional theory calculations (DFT). Notably, a series of Cu(I) and Cu(III) complexes were observed as key intermediates and iden...

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Detalles Bibliográficos
Autores principales: Xu, Runsheng, Cai, Rongrong, Zhou, Sixian, Zhou, Zhuoda, Li, Beibei, Xu, Dihui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6150210/
https://www.ncbi.nlm.nih.gov/pubmed/29113130
http://dx.doi.org/10.3390/molecules22111912

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6150210/
https://www.ncbi.nlm.nih.gov/pubmed/29113130
http://dx.doi.org/10.3390/molecules22111912

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