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9,10-Dihydrophenanthrene with Two Spiro(dibenzocycloheptatriene) Units: A Highly Strained Caged Hydrocarbon Exhibiting Reversible Electrochromic Behavior

The title dispiro hydrocarbon 1 was designed as a new electrochromic material. This multiply clamped hexaphenylethane-type electron donor was prepared from 2,2′-diiodobiphenyl via biphenyl-2,2′-diylbis(dibenzotropylium) 2(2+) salt. X-ray analysis of 1 revealed a highly strained structure as reflecte...

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Detalles Bibliográficos
Autores principales: Ishigaki, Yusuke, Hayashi, Yuki, Sugawara, Kazuma, Shimajiri, Takuya, Nojo, Wataru, Katoono, Ryo, Suzuki, Takanori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6150351/
https://www.ncbi.nlm.nih.gov/pubmed/29113057
http://dx.doi.org/10.3390/molecules22111900