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Unexpected Synthesis of a Bulky Bis-Pocket A(3)B-Type Meso-Cyano Porphyrin
A one-pot synthesis of bulky bis-pocket A(3)B-type meso-cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxi...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6150394/ https://www.ncbi.nlm.nih.gov/pubmed/29120395 http://dx.doi.org/10.3390/molecules22111941 |