Unexpected Synthesis of a Bulky Bis-Pocket A(3)B-Type Meso-Cyano Porphyrin

A one-pot synthesis of bulky bis-pocket A(3)B-type meso-cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxi...

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Autores principales: Liu, Ze-Yu, Mahmood, Mian HR, Wu, Jian-Zhong, Yang, Shu-Bao, Liu, Hai-Yang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6150394/
https://www.ncbi.nlm.nih.gov/pubmed/29120395
http://dx.doi.org/10.3390/molecules22111941
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author Liu, Ze-Yu
Mahmood, Mian HR
Wu, Jian-Zhong
Yang, Shu-Bao
Liu, Hai-Yang
author_facet Liu, Ze-Yu
Mahmood, Mian HR
Wu, Jian-Zhong
Yang, Shu-Bao
Liu, Hai-Yang
author_sort Liu, Ze-Yu
collection PubMed
description A one-pot synthesis of bulky bis-pocket A(3)B-type meso-cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxidant and the cyanating agent.
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spelling pubmed-61503942018-11-13 Unexpected Synthesis of a Bulky Bis-Pocket A(3)B-Type Meso-Cyano Porphyrin Liu, Ze-Yu Mahmood, Mian HR Wu, Jian-Zhong Yang, Shu-Bao Liu, Hai-Yang Molecules Communication A one-pot synthesis of bulky bis-pocket A(3)B-type meso-cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxidant and the cyanating agent. MDPI 2017-11-09 /pmc/articles/PMC6150394/ /pubmed/29120395 http://dx.doi.org/10.3390/molecules22111941 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Liu, Ze-Yu
Mahmood, Mian HR
Wu, Jian-Zhong
Yang, Shu-Bao
Liu, Hai-Yang
Unexpected Synthesis of a Bulky Bis-Pocket A(3)B-Type Meso-Cyano Porphyrin
title Unexpected Synthesis of a Bulky Bis-Pocket A(3)B-Type Meso-Cyano Porphyrin
title_full Unexpected Synthesis of a Bulky Bis-Pocket A(3)B-Type Meso-Cyano Porphyrin
title_fullStr Unexpected Synthesis of a Bulky Bis-Pocket A(3)B-Type Meso-Cyano Porphyrin
title_full_unstemmed Unexpected Synthesis of a Bulky Bis-Pocket A(3)B-Type Meso-Cyano Porphyrin
title_short Unexpected Synthesis of a Bulky Bis-Pocket A(3)B-Type Meso-Cyano Porphyrin
title_sort unexpected synthesis of a bulky bis-pocket a(3)b-type meso-cyano porphyrin
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6150394/
https://www.ncbi.nlm.nih.gov/pubmed/29120395
http://dx.doi.org/10.3390/molecules22111941
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