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Unexpected Synthesis of a Bulky Bis-Pocket A(3)B-Type Meso-Cyano Porphyrin

A one-pot synthesis of bulky bis-pocket A(3)B-type meso-cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxi...

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Detalles Bibliográficos
Autores principales: Liu, Ze-Yu, Mahmood, Mian HR, Wu, Jian-Zhong, Yang, Shu-Bao, Liu, Hai-Yang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6150394/
https://www.ncbi.nlm.nih.gov/pubmed/29120395
http://dx.doi.org/10.3390/molecules22111941

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