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Proton-Stabilized Photochemically Reversible E/Z Isomerization of Spiropyrans

[Image: see text] Spiropyrans undergo C(spiro)–O bond breaking to their ring-open protonated E-merocyanine form upon protonation and irradiation via an intermediate protonated Z-merocyanine isomer. We show that the extent of acid-induced ring opening is controlled by matching both the concentration...

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Detalles Bibliográficos
Autores principales: Kortekaas, L., Chen, J., Jacquemin, D., Browne, W. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6150689/
https://www.ncbi.nlm.nih.gov/pubmed/29847129
http://dx.doi.org/10.1021/acs.jpcb.8b03528