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N-Heterocyclic Carbene Coinage Metal Complexes of the Germanium-Rich Metalloid Clusters [Ge(9)R(3)](−) and [Ge(9)R(I)(2)](2−) with R = Si((i)Pr)(3) and R(I) = Si(TMS)(3)

We report on the synthesis of novel coinage metal NHC (N-heterocyclic carbene) compounds of the germanium-rich metalloid clusters [Ge(9)R(3)](−) and [Ge(9)R(I)(2)](2−) with R = Si((i)Pr)(3) and R(I) = Si(TMS)(3). NHC(Dipp)Cu{η(3)-Ge(9)R(3)} with R = Si((i)Pr)(3) (1) represents a less bulky silyl gro...

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Detalles Bibliográficos
Autores principales: Geitner, Felix S., Giebel, Michael A., Pöthig, Alexander, Fässler, Thomas F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152075/
https://www.ncbi.nlm.nih.gov/pubmed/28753928
http://dx.doi.org/10.3390/molecules22071204