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N-Heterocyclic Carbene Coinage Metal Complexes of the Germanium-Rich Metalloid Clusters [Ge(9)R(3)](−) and [Ge(9)R(I)(2)](2−) with R = Si((i)Pr)(3) and R(I) = Si(TMS)(3)
We report on the synthesis of novel coinage metal NHC (N-heterocyclic carbene) compounds of the germanium-rich metalloid clusters [Ge(9)R(3)](−) and [Ge(9)R(I)(2)](2−) with R = Si((i)Pr)(3) and R(I) = Si(TMS)(3). NHC(Dipp)Cu{η(3)-Ge(9)R(3)} with R = Si((i)Pr)(3) (1) represents a less bulky silyl gro...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152075/ https://www.ncbi.nlm.nih.gov/pubmed/28753928 http://dx.doi.org/10.3390/molecules22071204 |