Readily Available Chiral Benzimidazoles-Derived Guanidines as Organocatalysts in the Asymmetric α-Amination of 1,3-Dicarbonyl Compounds

The synthesis and the evaluation as organocatalysts of new chiral guanidines derived from benzimidazoles in the enantioselective α-amination of 1,3-dicarbonyl compounds using di-t-butylazodicarboxylate as aminating agent is herein disclosed. The catalysts are readily synthesized through the reaction...

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Detalles Bibliográficos
Autores principales: Benavent, Llorenç, Puccetti, Francesco, Baeza, Alejandro, Gómez-Martínez, Melania
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152235/
https://www.ncbi.nlm.nih.gov/pubmed/28800100
http://dx.doi.org/10.3390/molecules22081333

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152235/
https://www.ncbi.nlm.nih.gov/pubmed/28800100
http://dx.doi.org/10.3390/molecules22081333

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