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Trifluoroethoxy-Coated Phthalocyanine Catalyzes Perfluoroalkylation of Alkenes under Visible-Light Irradiation †

We disclose herein the perfluoroalkylation of alkenes catalyzed by trifluoroethoxy-coated zinc phthalocyanine under irradiation of visible light. Perfluoroalkyl iodides were nicely incorporated into unsaturated substrates, including alkyne, to provide perfluoroalkyl and iodide adducts in moderate to...

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Detalles Bibliográficos
Autores principales: Matsuzaki, Kohei, Hiromura, Tomoya, Amii, Hideki, Shibata, Norio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152348/
https://www.ncbi.nlm.nih.gov/pubmed/28686205
http://dx.doi.org/10.3390/molecules22071130