General Methodologies Toward cis-Fused Quinone Sesquiterpenoids. Enantiospecific Synthesis of the epi-Ilimaquinone Core Featuring Sc-Catalyzed Ring Expansion

A stereocontrolled approach to the cis-decalin framework of clerodane diterpenes and biologically active quinone sesquiterpenes is reported. Starting from an inexpensive optically pure tetrahydroindanone, Birch reductive alkylation builds two new contiguous chiral centers—one of which is quaternary...

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Detalles Bibliográficos
Autores principales: Kaplan, Hilan Z., Rendina, Victor L., Kingsbury, Jason S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152358/
https://www.ncbi.nlm.nih.gov/pubmed/28672821
http://dx.doi.org/10.3390/molecules22071041

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152358/
https://www.ncbi.nlm.nih.gov/pubmed/28672821
http://dx.doi.org/10.3390/molecules22071041

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