Metal-Free Regiodivergent Addition of Carbon Nucleophiles to α,β-Unsaturated Electrophiles

A mild and metal-free regiodivergent addition of carbon nucleophiles to α,β-unsaturated electrophiles was developed. Total 1,2-regioselectivity was observed in the addition of nitrobenzyl chloride derivative 1 to α,β-unsaturated aldehydes 2 in the presence of TDAE. Moreover, the reaction between p-n...

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Detalles Bibliográficos
Autores principales: Spitz, Cédric, Giuglio-Tonolo, Alain G., Terme, Thierry, Vanelle, Patrice
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152382/
https://www.ncbi.nlm.nih.gov/pubmed/28708088
http://dx.doi.org/10.3390/molecules22071178

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6152382/
https://www.ncbi.nlm.nih.gov/pubmed/28708088
http://dx.doi.org/10.3390/molecules22071178

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