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Gold Nanoparticles Deposited on Surface Modified Carbon Xerogels as Reusable Catalysts for Cyclohexane C-H Activation in the Presence of CO and Water

The use of gold as a promotor of alkane hydrocarboxylation is reported for the first time. Cyclohexane hydrocarboxylation to cyclohexanecarboxylic acid (up to 55% yield) with CO, water, and peroxodisulfate in a water/acetonitrile medium at circa 50 °C has been achieved in the presence of gold nanopa...

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Detalles Bibliográficos
Autores principales: Ribeiro, Ana Paula da Costa, Martins, Luísa Margarida Dias Ribeiro de Sousa, Carabineiro, Sónia Alexandra Correia, Figueiredo, José Luís, Pombeiro, Armando José Latourrette
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6154559/
https://www.ncbi.nlm.nih.gov/pubmed/28397772
http://dx.doi.org/10.3390/molecules22040603