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Thiazine-2-thiones as Masked 1-Azadienes in Cascade Dimerization Reactions

We report the unexpected formation of a 1-azadiene dimer from 4,6-diphenyl-3,6-dihydro-2H-1,3-thiazine-2-thiones under prolonged microwave irradiation. In this manner, thiazine-2-thiones act as “masked” 1-azadiene equivalents, which makes them useful synthetic tools to access complex heterocyclic fr...

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Detalles Bibliográficos
Autores principales: Kruithof, Art, Vande Velde, Christophe M. L., Ruijter, Eelco, Orru, Romano V. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6154663/
https://www.ncbi.nlm.nih.gov/pubmed/28350361
http://dx.doi.org/10.3390/molecules22040541