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Identifying the missing link in catalyst transfer polymerization

Nickel-catalyzed catalyst transfer polycondensation (CTP) of thiophenes is an efficient strategy for the controlled synthesis of polythiophenes. However, a detailed view of its reaction mechanism has remained elusive with unresolved questions regarding the geometry and bonding of critical Ni(0) thio...

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Detalles Bibliográficos
Autores principales: He, Weiying, Patrick, Brian O., Kennepohl, Pierre
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155128/
https://www.ncbi.nlm.nih.gov/pubmed/30250037
http://dx.doi.org/10.1038/s41467-018-06324-9