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Solventless Synthesis of Poly(pyrazolyl)phenyl-methane Ligands and Thermal Transformation of Tris(3,5-dimethylpyrazol-1-yl)phenylmethane

The solventless synthesis of tris(pyrazolyl)phenylmethane ligands of formula C(6)H(5)C(Pz(R2))(3) (R = H, Me), starting from PhCCl(3) and 3,5-dimethylpyrazole (Pz(Me2)) or pyrazole (Pz) was performed. The sterically crowded C(6)H(5)C(Pz(Me2))(3) is thermally transformed into the bis(pyrazolyl)(p-pyr...

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Detalles Bibliográficos
Autores principales: Rodríguez-Venegas, Edith, García-Báez, Efrén V., Martínez-Martínez, Francisco J., Cruz, Alejandro, Padilla-Martínez, Itzia I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155200/
https://www.ncbi.nlm.nih.gov/pubmed/28287474
http://dx.doi.org/10.3390/molecules22030441