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Looking Inside the Intramolecular C−H∙∙∙O Hydrogen Bond in Lactams Derived from α-Methylbenzylamine

Recently, strong evidence that supports the presence of an intramolecular C−H···O hydrogen bond in amides derived from the chiral auxiliary α-methylbenzylamine was disclosed. Due to the high importance of this chiral auxiliary in asymmetric synthesis, the inadvertent presence of this C−H···O interac...

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Detalles Bibliográficos
Autores principales: Mejía, Sandra, Hernández-Pérez, Julio M., Sandoval-Lira, Jacinto, Sartillo-Piscil, Fernando
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6155423/
https://www.ncbi.nlm.nih.gov/pubmed/28264508
http://dx.doi.org/10.3390/molecules22030361