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Synthesis of N-Heterocycle Substituted Silyl Ligands within the Coordination Sphere of Iron
[Image: see text] N-Heterocycle-substituted silyl iron complexes have been synthesized by nucleophilic substitution at trichlorosilyl ligands bound to iron. The homoleptic (tripyrrolyl)- and tris(3-methylindolyl)silyl groups were accessed from (Cl(3)Si)CpFe(CO)(2) (Cl(3)SiFp) by substitution of chlo...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6158677/ https://www.ncbi.nlm.nih.gov/pubmed/30270963 http://dx.doi.org/10.1021/acs.organomet.8b00399 |