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Synthesis of N-Heterocycle Substituted Silyl Ligands within the Coordination Sphere of Iron

[Image: see text] N-Heterocycle-substituted silyl iron complexes have been synthesized by nucleophilic substitution at trichlorosilyl ligands bound to iron. The homoleptic (tripyrrolyl)- and tris(3-methylindolyl)silyl groups were accessed from (Cl(3)Si)CpFe(CO)(2) (Cl(3)SiFp) by substitution of chlo...

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Detalles Bibliográficos
Autores principales:	Witteman, Léon, Lutz, Martin, Moret, Marc-Etienne
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2018
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6158677/ https://www.ncbi.nlm.nih.gov/pubmed/30270963 http://dx.doi.org/10.1021/acs.organomet.8b00399

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